尿素作为"极性疏水性"结基因:用于高耐久性全水下粘附
Kohei Kikkawa1, Yosuke Sumiya2, Kazuki Okazawa2
1Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Journal of the American Chemical Society
|July 20, 2024
概括
尿素作为"极性疏水"基因,使得水下粘合剂具有耐用性. 这一突破克服了水
科学领域:
- 材料科学
- 聚合物化学
- 表面化学
背景情况:
- 开发持久的水下粘合剂是具有挑战性的,因为自发的水化层形成会抑制粘合.
- 传统的结基因如尿素是极性和水友性,限制了它们在水环境中的有效性.
- 尿素作为"极性疏水"的独特特性以前未被用于粘合剂应用.
研究的目的:
- 研究尿素作为一种新的结基因,用于制造强大的水下粘合剂.
- 为了证明尿素基粘合剂在水环境下比尿素基粘合剂的性能优越.
- 探索尿基材料在水中增强粘附的机制.
主要方法:
- 合成的可自我修复的多乙聚合物.
- 在海水中的湿玻璃表面测试了基尿素基粘合剂的粘合强度和耐久性.
- 与使用尿素作为结基因的参考粘合剂进行性能比较.
主要成果:
- 与尿素相比,尿素与水的N-H质子交换显著较低,表明水分减少.
- 聚乙) 显示出在潮湿表面的特殊粘附性,在海水中保持超过一年的强度.
- 基于尿素的基准粘合剂在4天内失去了水中的耐用性,突出了尿素的优势.
结论:
- 尿素作为"极性疏水性"结基因,对于在水下粘合剂中实现脱水接口至关重要.
- 这项研究提出了一种新的策略,用于开发使用氨酸的非常耐用的全水下粘合剂.
- 这些发现对海洋工程,生物医学应用和水下修复有重要意义.
相关概念视频
Cohesion
54.2K
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a...
On a...
54.2K
Hydrogen Bonds
121.1K
Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
121.1K
Structure and Nomenclature of Thiols and Sulfides
4.6K
Thiols and sulfides are sulfur analogs of alcohols and ethers, respectively, where the sulfur atom takes the place of the oxygen atom. Thus, thiols are generally represented as RSH, where R is an alkyl substituent and —SH is the functional group. On the other hand, in sulfides, the central sulfur atom is bonded to two hydrocarbon groups on either side. Depending upon the type of group, sulfides can be either symmetrical or asymmetrical. Both thiols and sulfides display a bent geometry,...
4.6K
Molecular Shape and Polarity
60.1K
Dipole Moment of a Molecule
60.1K
Preparation and Reactions of Thiols
6.1K
Thiols are prepared using the hydrosulfide anion as a nucleophile in a nucleophilic substitution reaction with alkyl halides. For instance, bromobutane reacts with sodium hydrosulfide to give butanethiol.
6.1K
Surface Tension, Capillary Action, and Viscosity
27.7K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
27.7K


