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制备和优化由表面活性离子液体和非离子表面活性剂组成的有效油污分散剂
Masooma Nazar1, Aqeel Ahmad2, Syed Muhammad Shakil Hussain1
1Center for Integrative Petroleum Research (CIPR), College of Petroleum Engineering and Geosciences, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia.
ACS omega
|July 22, 2024
概括
这项研究开发了一种使用非离子表面活性剂和表面活性离子液体的绿色石油泄漏分散剂. 该配方显示出高效率,低毒性和快速生物降解性,用于更安全的水生环境修复.
科学领域:
- 环境化学环境化学
- 绿色化学 绿色化学
- 表面活性剂科学 表面活性剂科学
背景情况:
- 石油泄漏的常规化学分散剂由于有毒性和生物降解性差,造成环境风险.
- 开发有效和环保的替代品对于减轻漏油影响至关重要.
研究的目的:
- 综合和评估一个环保的石油泄漏整治配方.
- 将非离子表面活性剂 (Tween 80,Span 80) 与表面活性离子液体 (SAIL) 结合起来,以提高性能.
主要方法:
- 使用Tween 80,Span 80,[Bmim][Lausar]和[Cho][Mys]制定了一个新的分散剂.
- 评估乳液稳定性,表面张力,界面张力 (IFT) 和分散效率.
- 使用斑马鱼 (LC50) 评估急性毒性和28天内的生物降解性.
主要成果:
- 最佳配方 (F9) 显示出出色的乳液稳定性和3.52毫米的临界菌根度 (CMC).
- 各种原油的分散效率在70.12%至93.72%之间.
- 该配方具有低毒性 (LC50 = 450毫克L-1) 和快速生物降解性 (>60%在28天内).
结论:
- 开发的绿色配方提供了一个有希望的,有效的和安全的解决方案,用于石油泄漏的补救.
- 这种方法可以显著减少石油泄漏对环境的影响,并改善清理操作.
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