在Ti1-Mn合金中创纪录的超导过渡温度
Ying-Jie Zhang1, Yijie Zhu1, Qing Li1
1National Laboratory of Solid State Microstructures and Department of Physics, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China.
Journal of the American Chemical Society
|July 22, 2024
概括
在高压下,- (Ti-Mn) 合金的超导性得到增强,挑战了像这样的磁性元素总是阻碍超导性的观念.
科学领域:
- 凝聚物质物理学
- 材料科学
- 超导性
背景情况:
- (Mn) 的磁矩通常不利于超导.
- 在含有磁元素的材料中实现超导性通常是具有挑战性的.
研究的目的:
- 在高压下研究β相Ti-Mn合金的超导性.
- 探索磁场对超导的作用.
- 挑战超导体中的磁性杂质的传统理解.
主要方法:
- 用β相Ti-Mn合金进行高压实验.
- 用于结构分析的同步射线衍射.
- 支持实验发现的第一原则计算.
主要成果:
- 在Ti-Mn合金中达到约26K的超导过渡温度 (Tc).
- 尽管含有显著的,但仍观察到超导性增强.
- 上临界磁场在中压状态下超过了保利极限.
- 在压力下持续的细胞体积收缩下,β相结构保持稳定.
结论:
- 这项研究表明含有Mn的合金具有增强的超导性,这与已知的理论相矛盾.
- 高压可以令人惊地促进磁性材料的超导.
- 需要进一步的理论研究来充分解释观察到的Tc的压力依赖性.
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