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Updated: Jun 20, 2025

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework

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机器学习启发的分子设计,分离合成和X射线分析由S⋅⋅⋅N和S⋅⋅⋅S相互作用控制的基于Dithienobenzothiazole的半导体

Takuya Ogaki1,2, Yasunori Matsui1,2, Haruki Okamoto1

  • 1Department of Applied Chemistry, Graduate School of Engineering, Osaka Metropolitan University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan.

Chemistry (Weinheim an der Bergstrasse, Germany)
|July 22, 2024
PubMed
概括

合成了七种新的dithienobenzothiazole衍生物,以提高有机半导体的孔移动性. 分子包装和结接收器显著影响了电荷传输特性,导致特定化合物的有希望的移动性.

关键词:
晶体结构 晶体结构不同的合成分离.材料信息学 材料信息学有机场效应晶体管有机半导体有机半导体

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Preparation and Reactions of Sulfides02:26

Preparation and Reactions of Sulfides

Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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