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Updated: Jun 20, 2025

Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
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Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction

Published on: January 19, 2016

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低摩尔质量的循环聚L-乳化物:在固态中,循环和线性链的单独转化反应

Hans R Kricheldorf1, Steffen M Weidner2

  • 1Universität Hamburg, Institut für Technische Chemie und Makromolekulare Chemie, Bundesstr. 45, D-20146 Hamburg, Germany. hrkricheldorf@aol.de.

Soft matter
|July 23, 2024
PubMed
概括

这项研究使用 (II) 2-乙烯基酸盐合成了循环多聚化物 (cPLA). 化揭示了线性和循环链之间的明显的转化行为,由热力学控制控制.

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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

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Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer

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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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