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相关概念视频

Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
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Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
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Intermolecular forces (IMF) are electrostatic attractions arising from charge-charge interactions between molecules. The strength of the intermolecular force is influenced by the distance of separation between molecules. The forces significantly affect the interactions in solids and liquids, where the molecules are close together. In gases, IMFs become important only under high-pressure conditions (due to the proximity of gas molecules). Intermolecular forces dictate the physical properties of...
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相关实验视频

Updated: Jun 19, 2025

Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
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在化中的过渡共价性

Dmitry S Maltsev1,2, Darren M Driscoll1, Yuanpeng Zhang3

  • 1Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.

Journal of the American Chemical Society
|July 23, 2024
PubMed
概括

高温改变了UCl3中的 (U) 结合,产生更短的U-Cl结合,并增加了U 5f轨道的参与. 这揭示了在极端条件下U (III) 周围的独特结合环境.

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科学领域:

  • 无机化学
  • 材料科学
  • 物理化学

背景情况:

  • (U) 是核燃料中关键的活性元素.
  • 在高温下了解U的协调化学和结合是有限的.
  • 在极端条件下,U 5f轨道在结合中的作用尚未得到充分证实.

研究的目的:

  • 在高温下研究三化物 (UCl3) 的协调化学和结合.
  • 确定固体到化的相位过渡对U连接体距离和结合的影响.
  • 在极端热条件下阐明 U 5f 价值轨道的参与.

主要方法:

  • 在高温下研究UCl3的实验技术.
  • 用计算机建模分析结合相互作用.
  • 对U连接体距离和协调环境的分析.

主要成果:

  • 在固体到化的阶段过渡过程中观察到UCl3中平均U-连接体距离的收缩.
  • 形成显著的一小部分短暂的U-Cl键.
  • 增强了U 5f价值轨道在结合相互作用中的参与.

结论:

  • 极端温度会导致UCl3中的结环境发生显著的变化.
  • 形成一个具有不同的内部和外部协调子的异质结合环境.
  • 高温促进U 5f轨道在化学结合中的增强参与.