超磁性相位过渡在Dy0.5Ho0.5MnO3单晶中诱导了大的磁热效应
Wanting Yang1, Haiyang Chen2, Haohuan Peng1
1Department of Physics, Materials Genome Institute, Institute for Quantum Science and Technology, Shanghai University, Shanghai 200444, China. sxcao@shu.edu.cn.
Physical chemistry chemical physics : PCCP
|July 24, 2024
概括
这项研究探讨了用于磁性制冷的Dy0.5Ho0.5MnO3. 该材料显示了增强的磁热性质,使其成为低温冷却应用的有希望的材料.
科学领域:
- 凝聚物质物理学 凝聚物质物理学
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
背景情况:
- 磁性制冷利用磁热效应,稀土矿显示出有前途.
- 需要更深入地了解这些材料中的磁热效应.
研究的目的:
- 为了研究Dy0.5Ho0.5MnO3单晶的磁性和磁热性质.
- 评估其用于磁性制冷应用的潜力.
主要方法:
- 使用光学浮动区方法培养了Dy0.5Ho0.5MnO3的高质量单晶.
- 磁性,介电性,热容量和磁热性质得到了彻底的研究.
主要成果:
- 兴奋剂DyMnO3和HoMnO3修改了磁性,并将旋转重定位转移到较低的温度.
- 该材料在低温下表现出显著的负磁变化 (18 J kg-1 K-1) 和亚底波温度变化 (8.5 K).
- 沿a轴观察到增强的磁热热效应,这是由于磁晶异性质.
结论:
- 与母晶体相比,Dy0.5Ho0.5MnO3显示出优越的磁热性能.
- 它的特性使其成为高效的低温磁制冷的强大候选人.
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