溶解有机物质的分子量显著影响微塑料的光衰老
Jianrui Pan1, Shilong Zhang1, Xinran Qiu1
1College of Natural Resources and Environment, Northwest A&F University, Yangling, Shaanxi 712100, China.
Environmental science & technology
|July 24, 2024
概括
低分子量酸通过增加反应性物种,显著加速微塑料的光衰老. 这一发现对于了解水生生态系统中微塑料的环境命运至关重要.
科学领域:
- 环境科学 环境科学
- 聚合物化学 聚合物化学
- 水生化学 水生化学
背景情况:
- 水生环境中的微塑料 (MP) 的命运受到溶解有机物 (DOM) 的影响.
- DOM反应性与分子量 (MW) 有关,但其对MP衰老的影响还未得到充分研究.
研究的目的:
- 为了研究不同MW溶解有机物分量的对聚乙烯微塑料 (PSMP) 衰老的影响.
- 为了比较酸 (FA) 和酸 (HA) 对PSMP光衰老的影响.
主要方法:
- 在不同MWFA和HA的存在下,在紫外线照明下系统地调查PSMP老化.
- 对PSMP表面化学变化 (O/C比率) 和反应性物种生成的分析.
主要成果:
- 较低的MW FA (FA<1kDa) 显著增加了PSMP的O/C比率,表明了显著的老化.
- 由于更高的氧化还原能力,FA对PSMPs的光衰老效应比HA更强.
- FA<1kDa增加了50-290%的活性物种产量 (包括OH) 和25%的电子捐赠能力.
结论:
- 低分子量酸是水生系统中微塑料光衰老的关键驱动因素.
- 了解DOM分子重量对于预测微塑料环境命运至关重要.
- 这项研究为受有机物影响的微塑料老化机制提供了理论基础.
更多相关视频
相关概念视频
Polymers: Molecular Weight Distribution
3.3K
For any given polymer, the weight average molecular weight (Mw) is higher than, if not equal to, the number average molecular weight (Mn). The only situation in which the weight average molecular weight and the number average molecular weight are equal is when a polymer consists only of chains with equal molecular weight. However, this never happens in a synthetic polymer, since it is difficult to control the polymerization process up to a molecular level with accuracy to a hundred percent.
3.3K
Polymers: Defining Molecular Weight
2.8K
Unlike small molecules with definite molecular weights, polymers are a mixture of individual polymer chains of varying lengths, each with a unique molecular weight. So, the molecular weight of a polymer is expressed as an average value based on the average size of the polymer chains. The two most common forms of averages used for polymers are the number average molecular weight and weight average molecular weight.
The number average molecular weight (Mn) is the summation of the number...
The number average molecular weight (Mn) is the summation of the number...
2.8K
Molecular Weight of Step-Growth Polymers
2.2K
Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
2.2K


