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Updated: Jun 19, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Published on: July 30, 2017

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一个级联C(sp3) -H无效化,涉及C(alkyl),C(alkyl) -Pallada循环中间体

Liwei Zhou1,2, Xiahong Chen1, Qiong Peng3

  • 1Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education), National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, and Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha, Hunan, 410081, China.

Angewandte Chemie (International ed. in English)
|July 25, 2024
PubMed
概括

这项研究引入了一种新型的级反应,用于使用C(alkyl),C(alkyl) -palladacycles的C(sp3) -H无效化. 这种方法有效地从易于获得的前体中合成复杂的 pyridinediones.

关键词:
在C(sp3)−H激活过程中.在C,C-pallada循环中使用.DFT计算的计算方法级联反应是一种级联反应.循环化反应是一种循环化反应.

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