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含和的大豆油聚醇:对聚氨泡的机械性能和阻燃性的影响

Deniz Öztaşkin¹, Lütfullah Yusuf Yivlik^1,2, İlayda Acaroğlu Degitz¹

¹Department of Chemistry, Faculty of Arts and Science, Yıldız Technical University, İstanbul, Turkiye.

Turkish journal of chemistry

|July 25, 2024

概括

研究人员从可再生资源开发了基于和的新型生物聚合物,用于阻燃聚氨泡. 这些生物聚合物增强了热稳定性和阻燃性,没有漏,提供了可持续的替代方案.

科学领域:

材料科学材料科学材料科学
聚合物化学聚合物化学
可持续化学可持续化学

背景情况:

越来越多的人对使用可再生资源的环保材料的需求.
在聚合物中需要具有非水性质的无素阻燃剂.
聚氨 (PU) 泡被广泛使用,但通常需要阻燃剂添加剂.

研究的目的:

设计和合成用于PU泡生产的新型-基生物聚合物.
评估包含这些生物聚合物的PU泡的阻燃性和机械性能.
研究生物聚合物含量对泡特性 (如热稳定性,易燃性,密度和机械强度) 的影响.

主要方法:

通过用含和含四醇 (DYM) 的氧化大豆油的环开环合成双功能的多 (ESBO-DYM).
使用不同数量的合成ESBO-DYM聚合物的聚氨泡的配方.
泡属性的表征包括机械强度,热稳定性 (TGA),限制氧指数 (LOI),密度和形态 (SEM).

主要成果:

在PU泡中增加含量提高了热稳定性.
100%的ESBO-DYM聚醇配方在600°C时达到22.9%的极限氧指数 (LOI) 和17%的最大碳产量.
加入ESBO-DYM降低了压缩强度和泡密度,最高的ESBO-DYM泡达到29.1kg/m3密度.

结论:

阻燃聚氨泡可以成功地使用可再生的基生物聚合物制成.
合成的ESBO-DYM聚醇提供了一种可持续和有效的方法来提高PU泡的阻燃性和热稳定性.
进一步的研究可以优化配方,以平衡特定应用的阻燃性和机械性能.

关键词:

氧化过氧化的大豆油.阻燃性阻燃性是一种阻燃性.是一种的物质.聚氨泡是一种聚氨泡可再生资源是可再生的资源.

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