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Updated: Jun 19, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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具有七等价值Re (d0) 中心的aza-金属循环

Qianhang Wang1, Yarong Wang2, Yue Zhao1

  • 1School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, P.R. China. jiangwf@dlut.edu.cn.

Dalton transactions (Cambridge, England : 2003)
|July 25, 2024
PubMed
概括

研究人员从前体中合成了新的 (VII) 亚金属循环. 这些合金属循环虽然非芳香,但具有独特的电子特性,扩大了晚期过渡金属化学的范围.

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Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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