比较评估激光电离和iKnife与快速蒸发电离质谱和机器学习相结合,用于Larimichthys crocea的地理认证
Weibo Lu1, Honghai Wang1, Lijun Ge1
1Collaborative Innovation Center of Seafood Deep Processing, Zhejiang Province Joint Key Laboratory of Aquatic Products Processing, Institute of Seafood, Zhejiang Gongshang University, Hangzhou, China.
Food chemistry
|July 25, 2024
概括
使用激光辅助快速蒸发电离质谱 (LA-REIMS) 和机器学习 (ML) 的新方法准确地验证了大黄 (LYC) 的地理来源. 这项技术支持海鲜行业的可追溯性.
科学领域:
- 分析化学 分析化学
- 食品科学 食品科学 食品科学
- 生物技术是生物技术.
背景情况:
- 鱼 (Larimichthys crocea,简称LYC) 是一个经济上重要的海洋鱼类.
- 不准确的LYC地理标签可能会对消费者信任和市场价值产生负面影响.
- 建立可靠的原产地认证方法对于水产品行业至关重要.
研究的目的:
- 开发和验证一种新的方法来确定Larimichthys crocer.的地理真实性.
- 为了比较激光辅助快速蒸发电离质谱法 (LA-REIMS) 与其他技术的有效性.
- 创建一个强大的机器学习 (ML) 模型,用于准确的来源追踪.
主要方法:
- 开发一个激光辅助的快速蒸发电离质谱仪 (LA-REIMS) 系统用于样本分析.
- 来自中国六个不同的地理区域的LYC样本的分析.
- 应用六个机器学习分类器用于地理起源建模.
- 优化超参数和特征工程,用于模型增强.
主要成果:
- 由于减少热损伤,自动化和易于使用,LA-REIMS方法在iKnife上表现出优越性.
- 分析确定了798个不同地理来源的特征性离子.
- Chi2(15%) -KNN模型实现了高精度,训练精度为98.4 ± 0.9%,测试精度为98.5 ± 1.4%.
- 开发的方法证明了LYC起源追踪的快速,准确和智能.
结论:
- 通过LA-REIMS/ML方法,提供了一种有效的解决方案,用于验证Larimichthys crocea的地理来源.
- 这项技术为加强海鲜行业内可追溯性系统提供了巨大的潜力.
- 这些发现支持开发水产品的强有力的质量控制和消费者保护措施.
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