在烤过程中,芝麻中的素的化学和结构转化
Zhao Qin1, Tian-Pei Zhao2, Meng-Ke He2
1College of Food Science and Engineering & Institute of Special Oilseed Processing and Technology, Henan University of Technology, Zhengzhou 450001, China; Food Laboratory of Zhongyuan, Luohe 462300, China.
International journal of biological macromolecules
|July 25, 2024
概括
芝麻种子的树皮红素在烤过程中经历了显著的结构变化,随着温度的提高,碳水化合物被分解,改变了红素的组成. 这种红素降解会影响芝麻油的氧化稳定性.
科学领域:
- 食品化学 食品化学
- 生物质降解 生物质降解
- 红素化学 红素化学
背景情况:
- 芝麻种子外红素 (LSSH) 在芝麻产品的整体成分和潜在应用中起着重要作用.
- 了解素在热处理过程中的行为,如烤,对于优化食品质量和稳定性至关重要.
研究的目的:
- 为了研究在190-250°C的温度下烤过程中,从芝麻种中取出的磨木木质素 (MWL) 的结构变化.
- 阐明红素降解的机制及其对芝麻油氧化稳定性的贡献.
主要方法:
- 从受控烤条件下 (190-250°C30分钟) 接受的芝麻种子外样本中,分析磨木质素 (MWL) 分数.
- 碳水化合物降解的量化,分子重量的变化,素类型比例 (H,G,S,C) 和关键的单位间联系 (β-O-4,β-β).
- 测量酸基生成的过程.
主要成果:
- 烤温度的提高导致了与红素相关的碳水化合物的显著降解,降低了总糖含量.
- 红素分子量下降,而由于脱氧化,H型红素的比例增加.
- 关键的木质素连接 (β-O-4,β-β) 断裂,而基基团随着烤温度的提高而增加,表明降解和凝结.
结论:
- 在烤过程中,芝麻种子的树皮质素经历复杂的降解和凝结反应.
- 观察到的红素结构的变化,包括键裂和基的增加,与影响芝麻油氧化稳定的化合物的生成有关.
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