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Updated: Jun 19, 2025

Preparation of Binary and Ternary Deep Eutectic Systems
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Preparation of Binary and Ternary Deep Eutectic Systems

Published on: October 31, 2019

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紧绳上的深度环氧溶剂:平衡混合的和

Adriaan van den Bruinhorst1, Chiara Corsini1, Guillaume Depraetère1

  • 1Ionic Liquids Group, Laboratoire de Chimie de l'École Normale Supérieure de Lyon, Centre Nationale de Recherche Scientifique, and Université de Lyon, 69364 Lyon, France. adriaan.van-den-bruinhorst@ens-lyon.fr.

Faraday discussions
|July 26, 2024
PubMed
概括

由于有利的吉布斯能量,深溶性溶剂 (DES) 呈现出很大的点陷. 这项研究揭示了,虽然一些DESs是度主导的,但其他则是度主导的,独立于键.

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Separation of Aldehydes and Reactive Ketones from Mixtures Using a Bisulfite Extraction Protocol

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High-pressure Sapphire Cell for Phase Equilibria Measurements of CO2/Organic/Water Systems05:46

High-pressure Sapphire Cell for Phase Equilibria Measurements of CO2/Organic/Water Systems

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相关概念视频

Entropy and Solvation02:05

Entropy and Solvation

The process of surrounding a solute with solvent is called solvation. It involves evenly distributing the solute within the solvent. The rule of thumb for determining a solvent for a given compound is that like dissolves like. A good solvent has molecular characteristics similar to those of the compound to be dissolved. For example, polar solutions dissolve polar solutes, and apolar solvents dissolve apolar solutes. A polar solvent is a solvent that has a high dielectric constant (ϵ...
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Chemical and Solubility Equilibria02:21

Chemical and Solubility Equilibria

The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ΔGsolution is expressed as the balance of ΔGinteraction against the always-favorable free-energy of mixing, ΔGmixing. Solution formation is favorable if  ΔGsolution is less than zero, whereas it is unfavorable if ΔGsolution is greater than zero. In short, for a solution to form and complete dissolution to take place,...
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Enthalpy of Solution

There are two criteria that favor, but do not guarantee, the spontaneous formation of a solution:
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Energetics of Solution Formation02:35

Energetics of Solution Formation

The formation of a solution is an example of a spontaneous process, which is a process that occurs under specified conditions without energy from some external source.
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Aqueous Solutions and Heats of Hydration

Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
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Entropy02:39

Entropy

Salt particles that have dissolved in water never spontaneously come back together in solution to reform solid particles. Moreover, a gas that has expanded in a vacuum remains dispersed and never spontaneously reassembles. The unidirectional nature of these phenomena is the result of a thermodynamic state function called entropy (S). Entropy is the measure of the extent to which the energy is dispersed throughout a system, or in other words, it is proportional to the degree of disorder of a...
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