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Updated: Jun 19, 2025

Preparation of N-2-alkoxyvinylsulfonamides from N-tosyl-1,2,3-triazoles and Subsequent Conversion to Substituted Phthalans and Phenethylamines
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通过相转移催化方法对硫胺胺的S-化

Andrew T Champlin1, Na Yeon Kwon1, Jonathan A Ellman1

  • 1Department of Chemistry, Yale University, 225 Prospect St., New Haven, CT 06520, USA.

Angewandte Chemie (International ed. in English)
|July 26, 2024
PubMed
概括

使用相转移催化剂 (PTC) 和一种新型的保护组合成了化硫化合物. 这种方法可以在低温下对N-acylsulfenamides进行抗选择性化,从而产生有价值的硫胺中间体.

关键词:
基化是一种基化.具有反选择性 (enantioselectivity) 的一个特性.阶段转移催化反应的催化硫的存在是因为硫.合成方法 合成方法

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