纯的火花等离子烧结:微观结构和机械特性
Satyavan Digole1, Sanoj Karki1, Manoj Mugale1
1Department of Mechanical Engineering, Cleveland State University, Cleveland, OH 44115, USA.
Materials (Basel, Switzerland)
|July 27, 2024
概括
火花等离子烧结 (SPS) 增强了纯 (Ti) 的性能. 优化SPS温度显著影响Ti.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是一种金工业.
- 制造业 工程 制造工程
背景情况:
- (Ti) 是一个多功能金属,对航空航天和生物医学应用至关重要.
- 火花等离子烧结 (SPS) 是一种用于改善Ti特性的先进技术.
- 优化SPS参数是释放Ti全部潜力的关键.
研究的目的:
- 研究SPS温度对纯微观结构和机械性能的影响.
- 为了确定最佳的SPS温度来提高Ti的性能.
- 在SPS过程中分析相位形成和粒度结构演变.
主要方法:
- 纯样本在800至1400°C的温度下使用SPS烧结.
- 烧结是在60MPa进行的,在气氛中停留时间为5分钟.
- 微结构分析涉及X射线衍射 (XRD),扫描电子显微镜 (SEM) 和能量分散式X射线光谱 (EDS).
主要成果:
- 所有经过SPS处理的Ti样本都实现了高相对密度 (>99%).
- 烧结温度显著影响了颗粒大小 (1057微米),拉力收益强度 (488700MPa),最终拉力强度 (597792MPa) 和可塑性 (47%).
- 在所有测试温度中,XRD证实了单相α-Ti (六角密封结构) 的存在.
结论:
- 在生产密集,高品质的纯方面,SPS是有效的.
- 在定制Ti的机械性能和微观结构时,SPS温度是关键因素.
- 这项研究为优化SPS处理Ti的高级应用提供了洞察力.
相关概念视频
Types of Chemical Bonds
Chemical bonding theories were pioneered by American chemist Gilbert N. Lewis. He developed a model called the Lewis model to explain the type and formation of different bonds. Chemical bonding is central to chemistry; it explains how atoms or ions bond together to form molecules. It explains why some bonds are strong and others are weak, or why one carbon bonds with two oxygens and not three; why water is H2O and not H4O.
Covalent Bonding and Lewis Structures
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes
The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified petroleum gas (LPG), fuel oil, gasoline, diesel fuel, and...
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified petroleum gas (LPG), fuel oil, gasoline, diesel fuel, and...
Mass Spectrometry: Molecular Fragmentation Overview
The ionization of a molecule into a molecular ion inside the mass spectrometer causes instability in the molecule's structure due to the loss of an electron. This eventually leads to the fragmentation or breaking of some bonds in the molecule. The fragmentation occurs predominantly at specific bonds to yield relatively stable fragments.
One type of fragmentation pattern is the cleavage of a single bond in the molecular ion. The cleavage leads to a radical and a cation. The cleavage can occur at...
One type of fragmentation pattern is the cleavage of a single bond in the molecular ion. The cleavage leads to a radical and a cation. The cleavage can occur at...
Radical Formation: Homolysis
A bond is formed between two atoms by sharing two electrons. When this bond is broken by supplying sufficient energy, either two electrons can be taken up by one atom forming ions by the cleavage called heterolysis, or the two electrons are shared by two atoms, with one each creating radicals by the cleavage called homolysis.
Atomic Absorption Spectroscopy: Atomization Methods
Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the aerosol...


