对UVC辐射低密度聚乙烯 (LDPE) 食品包装的热发光和ATR-FTIR研究
C Boronat1, V Correcher2, J F Benavente2
1Department of Inorganic Chemistry, Faculty of Sciences, National University of Distance Education (UNED), Av. de Esparta s/n, 28232 Madrid, Spain; Department of Environment, Centre for Energy, Environment and Technology Research (CIEMAT), Av. Complutense 40, 28040 Madrid, Spain.
概括
这项研究研究了紫外线C (UVC) 对低密度聚乙烯 (LDPE) 包装的影响. 在LDPE下的热发光剂量计 (TLD) 准确检测到UVC,CaF2:Dy (TLD-200) 证明是可重复使用,低成本的食品处理监测最有效的.
科学领域:
- 材料科学 材料科学 材料科学
- 辐射物理 辐射物理
- 食品科学 食品科学 食品科学
背景情况:
- 紫外线C (UVC) 辐射在食品加工中用于消毒.
- 评估紫外线的有效性需要精确的剂量测量,特别是对于包装材料.
- 低密度聚乙烯 (LDPE) 是一种常见的食品包装材料,易受辐射影响.
研究的目的:
- 评估紫外线辐射对LDPE食品包装的影响.
- 评估各种热发光剂量计 (TLD) 在检测通过LDPE传输的UVC辐射方面的有效性.
- 为了确定监测基于UVC的食品处理程序的最佳TLD.
主要方法:
- 在LDPE样本的UVC辐射下放置TLD.
- 分析LDPE的结构变化使用减弱总反射率里埃变换红外光谱学 (ATR-FTIR).
- 来自不同TLD材料的UVC诱导热发光 (TL) 排放的测量和动态分析 (计算机化发光曲线解卷 - CGCD).
- 对TLD反应的比较研究,包括光转移 (PTTL) 效应和火处理的影响.
主要成果:
- 紫外线检测在一个小时后是准确的,验证TLD优化食品处理.
- ATR-FTIR显示了LDPE的轻微变化 (传导率<8%),可能是由于CH断裂和CC键振动,但变化也可能是LDPE固有的.
- TL的动力分析揭示了UVC诱导的陷电荷激活,电离,漂白和PTTL效应.
- LDPE放大了UVC-TL反应,TLD之间强度的差异 (GR-200 > TLD-100 > TLD-400 > TLD-200).
- TLD-200 (CaF2:Dy) 已证明适用于UVC检测,具有一致的响应和最小的PTTL,可重复使用,低成本测量,无需回火.
结论:
- CaF2:Dy (TLD-200) 是通过LDPE包装检测UVC辐射的最有效的TLD.
- 该研究提供了一种低成本,可重复使用的方法来监测UVC食品处理过程.
- 了解TLD材料特性和PTTL效应对于准确的UVC剂量测量至关重要.
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