在污染的土壤中预测BTEX挥发,基于吸附电能理论
Yongxiang Han1, Yaqi Sheng1, Jiating Zhao2
1Department of Environmental Science, Zhejiang University, Hangzhou, 310058, China.
Environmental pollution (Barking, Essex : 1987)
|July 28, 2024
概括
一个新的模型预测了土壤中的初始挥发性度 (Cs0),简化了对挥发性有机污染物 (VOC) 迁移的评估. 这种方法提供了一种快速而经济的方法来量化土壤中BTEX污染.
科学领域:
- 环境科学 环境科学
- 土壤科学 土壤科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 最初的挥发性度 (Cs0) 是挥发性有机污染物 (VOC) 从土壤迁移的关键.
- 目前的Cs0获取方法耗时且劳动密集.
研究的目的:
- 为Cs0.开发一个实用的预测模型.
- 将土壤特性与BTEX挥发相关联.
- 为受污染的地点提供快速准确的评估方法.
主要方法:
- 理论分析和实验模拟.
- 土壤孔隙结构和尺寸分布分析的碎形理论.
- 根据孔径大小计算吸附潜在能量的计算.
- 将土壤参数 (有机物质,水分) 和BTEX属性结合到模型中.
主要成果:
- 土壤毛孔大小分布通过吸附潜在能量影响BTEX挥发.
- 使用红土的模型验证显示最大相对误差为24.2%,RMSE为11.7%.
- 该模型准确地预测了Cs0,简化了VOC排放评估.
结论:
- 开发的模型提供了一种简单,快速和准确的方法来评估由于BTEX污染而导致的土壤蒸汽排放.
- 这为污染场所的挥发性BTEX量化提供了一种经济实用的方法.
- 该研究为监测,控制和修复BTEX污染土壤提供了有价值的数据.
相关概念视频
Volatilization
376
Volatilization gravimetry is an analytical technique that measures the mass lost due to the volatilization of the substance. This technique is used to estimate the amount of volatile material in a sample. To perform this method, heat a known amount of the sample to a high temperature in a crucible or other suitable vessel. The volatile substance in the sample evaporates, and the vapor is completely expelled from the crucible either by heating the sample or bubbling a stream of inert gas through...
376
Ideal Solutions
19.4K
According to Raoult’s law, the partial vapor pressure of a solvent in a solution is equal or identical to the vapor pressure of the pure solvent multiplied by its mole fraction in the solution. However, Raoult's Law is only valid for ideal solutions. For a solution to be ideal, the solvent-solute interaction must be just as strong as a solvent-solvent or solute-solute interaction. This suggests that both the solute and the solvent would use the same amount of energy to escape to the...
19.4K
Vapor Pressure Lowering
26.4K
The equilibrium vapor pressure of a liquid is the pressure exerted by its gaseous phase when vaporization and condensation are occurring at equal rates:
Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution....
Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution....
26.4K
Bioremediation
18.2K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.2K
Freezing Point Depression and Boiling Point Elevation
34.6K
Boiling Point Elevation
The boiling point of a liquid is the temperature at which its vapor pressure is equal to ambient atmospheric pressure. Since the vapor pressure of a solution is lowered due to the presence of nonvolatile solutes, it stands to reason that the solution’s boiling point will subsequently be increased. Vapor pressure increases with temperature, and so a solution will require a higher temperature than will pure solvent to achieve any given vapor pressure, including one...
The boiling point of a liquid is the temperature at which its vapor pressure is equal to ambient atmospheric pressure. Since the vapor pressure of a solution is lowered due to the presence of nonvolatile solutes, it stands to reason that the solution’s boiling point will subsequently be increased. Vapor pressure increases with temperature, and so a solution will require a higher temperature than will pure solvent to achieve any given vapor pressure, including one...
34.6K
Physical Properties Affecting Solubility
22.5K
Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
22.5K


