用增强的AMP-藻酸盐珠子,用于有效和选择性地从强酸性介质中去除
Qiang Jin1,2,3, Xinya Diao1,2, Ye Fan1,2
1MOE Frontiers Science Center for Rare Isotopes, Lanzhou University, Lanzhou 730000, China.
ACS omega
|July 29, 2024
概括
用增强的氨基基酸-酸 (ACS) 珠子显示了用于去除放射性的增强机械强度. 这些ACS珠子具有高的Cs+吸附能力和选择性,为高水平液体废物处理提供了有前途的解决方案.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 核废物管理 核废物管理
背景情况:
- 聚酸 (AMP) 对从高水平液体废物 (HLLW) 中去除Cs+具有很高的选择性.
- 由于AMP的微晶结构和细粉体形态,阻碍了工业应用.
- 酸颗粒提供了潜力,但可能会产生机械强度不足的珠子.
研究的目的:
- 开发基于AMP的强大的离子交换器,以有效地去除放射性.
- 通过加强二氧化来增强AMP-酸珠的机械性能.
- 为了评估与二氧化增强的AMP-甲基酸盐 (ACS) 珠子在酸性溶液中的Cs+吸附的性能.
主要方法:
- 用于制备加强的AMP-甲基酸盐 (ACS) 珠子.
- 制造的珠子的机械强度测试.
- 批量吸附实验以确定Cs+吸收动力学和容量.
- 对模拟HLLW中的共存金属离子进行选择性研究.
- 持续Cs+去除评估的列实验.
主要成果:
- 添加显著提高了珠子的机械强度,最佳AMP/比为1.0.
- Cs+吸附遵循非线性伪二次动态模型,并适应兰格穆尔等热法.
- 高Cs+分布系数 (∼1.6 × 10^2 mL/g) 观察到即使在8.0mol/L HNO3.0中也是如此.
- 最大Cs+交换能力在3.0mol/L HNO3.3中达到23.9 mg/g.
- 对于其他八种金属离子 (分离系数>145),ACS珠子对Cs+具有很好的选择性.
- 柱体实验证实了使用ACS珠作为静止相的有效Cs+去除.
结论:
- 增强有效地提高AMP-甲基珠的机械稳定性.
- 在酸性条件下,ACS珠子表现出高容量,优良的选择性和良好的Cs+去除性能.
- 这些发现突出了ACS珠子在HLLW的放射管理中的工业应用的潜力.
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