挖掘到四化的内在负热膨胀
James Louis-Jean1, Brian L Scott2, Harry Jang1
1Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Parkway, Las Vegas, Nevada 89154, United States.
ACS omega
|July 29, 2024
概括
四化物 (UF4) 在室温下表现出负热膨胀. 这种现象与原子的"吉他弦效应"有关,影响-距离.
科学领域:
- 固态化学 固态化学
- 材料科学 材料科学 材料科学
- 晶体学 晶体学是指结晶学.
背景情况:
- 负热膨胀 (NTE) 是一种在某些材料中观察到的反直觉性质.
- 了解化合物中的NTE对于核材料科学至关重要.
研究的目的:
- 为了研究四化物 (UF4) 在室温以下的内在负热膨胀.
- 阐明在UF4中导致NTE的结构机制.
主要方法:
- 单晶X射线衍射在可变温度 (100K,200K,300K) 上.
- 对原子的原子位移参数 (ADP) 的分析.
- 基于单元细胞参数和原子间距离的结构特征.
主要成果:
- 在加热时,UF4显示负热膨胀,单元细胞体积,a和c格子参数下降.
- 温度升高导致链内,链间和层间的U-U距离降低.
- 原子的"吉他弦效应"被认为是U-U距离收缩的起源.
结论:
- 在UF4中,NTE归因于U(2) 子网络在a和c轴上的收缩.
- U-U距离和ADP之间的相关性表明观察到的膨胀的振动起源.
- 该研究确立了原子振动和UF4中的宏观热膨胀之间的联系.
相关概念视频
Thermal Strain
874
Thermal strain is a concept that arises when we consider how temperature changes affect structures. Unlike the conventional assumption that structures remain constant under load, real-world scenarios often involve temperature fluctuations that can significantly impact these structures. Consider a homogeneous rod with a uniform cross-section resting freely on a flat horizontal surface. If the rod's temperature increases, the rod elongates. This elongation is proportional to the temperature...
874
Thermal Expansion
4.3K
The expansion of alcohol in a thermometer is one of many commonly encountered examples of thermal expansion, which is the change in size or volume of a given system as its temperature changes. The most visible example is the expansion of hot air. When air is heated, it expands and becomes less dense than the surrounding air, which then exerts an upward force on the hot air to, for example, make steam and smoke rise, and hot air balloons float. The same behavior happens in all liquids and gases,...
4.3K
Thermal expansion and Thermal stress: Problem Solving
1.1K
San Francisco's Golden Gate Bridge is exposed to temperatures ranging from -15 °C to 40 °C. At its coldest, the main span of the bridge is 1275 m long. Assuming that the bridge is made entirely of steel, what is the change in its length between these temperatures?
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in...
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in...
1.1K
Thermal Stress
2.4K
If the temperature of an object is changed while it is prevented from expanding or contracting, the object is subjected to stress. The stress is compressive if the object expands in the absence of constraint and tensile if it contracts. This stress resulting from temperature change is known as thermal stress. It can be quite large and can cause damage. To avoid this stress, engineers may design components so they can expand and contract freely. For instance, on highways, gaps are deliberately...
2.4K
Electron Affinity
35.4K
The electron affinity (EA) is the energy change for adding an electron to a gaseous atom to form an anion (negative ion).
35.4K
Nuclear Transmutation
17.5K
Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
17.5K


