优化有机太阳能电池的活性层形态通过构建随机共聚物与简单的第三单位
Qian Xie1, Chunyu Qiao1, Jie Fang1
1Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang, 330096, China.
Macromolecular rapid communications
|July 29, 2024
概括
修改聚合物PM6与二二氧化 (2FT) 单位提高了晶度和有机太阳能电池的性能. 狄基亚诺-二烯 (2CNT) 单元具有相反的效果,但三元制装置实现了高效率.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 有机电子 有机电子
背景情况:
- 有机太阳能电池 (OSC) 的性能高度依赖于供体聚合物的分子结构和形态.
- 优化聚合物骨干的共平面性和结晶性对于高效的电荷传输和设备效率至关重要.
研究的目的:
- 通过随机的共聚化,研究将二替代型二烯 (2FT) 和二替代型二烯 (2CNT) 单元纳入PM6聚合物骨干中的影响.
- 为了将结构修改与分子结晶度,形态,电荷传输特性以及有机太阳能电池的功率转换效率 (PCE) 的变化相关联.
主要方法:
- 用2FT和2CNT单位随机共聚聚合物PM6的随机共聚合.
- 由此产生的共聚合物的分子结构,共平面性和结晶性的表征.
- 使用这些改性聚合物制造有机太阳能电池的制造和性能测试.
- 在活性层中分析电荷载体流动性和形态.
主要成果:
- 结合2FT单元增强了聚合物共平面性和分子结晶性,从而改善了PM6-10%2FT:IT4F基础的OSC中的电荷流动性和PCE12.65%.
- 引入2CNT单元降低了共平度和结晶度,导致2CN系列随机共聚合物的PCE较低 (<12%).
- 一个三元装置 (PM6:L8-BO:PM6-20%2CN) 由于增强的开通电路电压,实现了19%的优异PCE.
结论:
- 通过引入特定的结构单元 (如2FT) 来增强供体聚合物骨干的共平面性,可以显著改善分子晶体性.
- 优化的聚合物结晶性和脊柱共平性导致有机太阳能电池的有利形态和增强的电荷传输.
- 战略分子设计,包括使用三元混合物,为实现高性能有机太阳能电池提供了一个有希望的途径.
更多相关视频
06:49In situ Grazing Incidence Small Angle X-ray Scattering on Roll-To-Roll Coating of Organic Solar Cells with Laboratory X-ray Instrumentation
Published on: March 2, 2021
6.2K
07:32Printing Fabrication of Bulk Heterojunction Solar Cells and In Situ Morphology Characterization
Published on: January 29, 2017
11.1K
相关概念视频
Characteristics and Nomenclature of Copolymers
2.5K
Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
2.5K
Step-Growth Polymerization: Overview
3.4K
Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
Many natural and synthetic polymers are produced by...
3.4K
