阿泽拉酸共聚塑剂的合成及其在PVC中的应用
Wanjing Zhang1, Liyan Wang1, Hong Chen1
1School of Petrochemical Engineering, Shenyang University of Technology Liaoyang 111003 P. R. China wangliyan0122@163.com.
RSC advances
|July 30, 2024
概括
由2-甲基-1,3-二醇 (MPO) 制成的新型生物基共聚增塑剂在增塑聚乙烯 (PVC) 中表现出色. 最佳配方,PHMAZ-45,提供了一个可持续的替代品.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 可持续的塑料 可持续的塑料
背景情况:
- 传统的塑化剂,如甲酸,对环境和健康构成风险.
- 开发更安全,生物基替代品对于塑料行业至关重要.
- 合聚合物为特定应用提供可调节的特性.
研究的目的:
- 为了合成和表征基于2-甲基-1,3-二醇 (MPO),阿泽莱酸和烯基醇的新型共聚塑性剂.
- 评估这些共聚合物 (PHMAZ) 在聚乙烯 (PVC) 上的塑化效率.
- 评估PHMAZ的潜力,作为一种可持续的替代品,以替代甲酸.
主要方法:
- 通过直接化融化聚凝合成PHMAZ共聚合物的合成.
- 使用红外光谱学 (IR) 和核磁共振 (NMR) 光谱学进行结构性表征.
- 通过凝透色谱 (GPC) 确定分子重量.
- 使用差分扫描热度计 (DSC) 和电子通用测试机对PVC塑化效应的评估.
主要成果:
- 成功合成了PHMAZ共聚合物,其分子量在2000-3000之间.
- 观察到PHMAZ-45 (45%MPO含量) 的最佳塑化效果.
- PHMAZ-45的结果是PVC玻璃过渡温度为-35°C,破裂时的延长率为908.4%,塑化效率为254.5%.
- 塑化效应在MPO含量高达45%时增加,然后下降.
结论:
- 对于PVC而言,PHMAZ共聚合物,特别是PHMAZ-45,具有优越的塑化性能.
- 生物原料的使用和稳定的制备过程突显了它们的工业潜力.
- 这些新型共聚合物代表了对危险的甲酸盐增塑剂的有希望的,环保的替代品.
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