改性青排放的特征及其对环境负担的影响:对成分变化和危害评估的洞察力
Lingwen Li1, Tao Zhou1, Liping Cao1
1School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin, Heilongjiang 150090, PR China.
Journal of hazardous materials
|July 30, 2024
概括
将轮胎回收成改性青 (RMA) 产生危险排放. 这项研究量化了这些排放,发现多环芳 (PAH) 是臭氧和气溶形成的主要贡献者.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 改性青 (RMA) 为废轮胎回收提供了一个可持续的解决方案.
- 人们对RMA生产和使用期间的有害烟雾排放存在担忧.
- 了解排放特征对于环境风险评估至关重要.
研究的目的:
- 在热条件下分析RMA的排放行为,重点关注碎大小.
- 量化臭氧形成潜力 (OFP) 和二次有机气溶形成潜力 (SOAFP).
- 确定导致环境负担的关键污染物及其来源.
主要方法:
- 使用一个专门的设备来测量RMA的排放量.
- 不同的粉碎大小和热暴露时间.
- 硫化 (H2S),挥发性有机化合物 (VOC) 和多环芳 (PAH) 的量化排放.
主要成果:
- 观察到明显的排放时间:H2S (0-150分钟),VOC (0-270分钟).
- 多环芳 (PAHs) 是OFP的主要贡献者 (约. 65%) 和SOAFP (25%-60%) 的产品.
- 排放源从转向石油青,随着日益增加的热暴露.
结论:
- 粉碎的尺寸和热持续时间显著影响VOC排放和环境负担.
- 多氧化和高分子量亚利法性碳化合物 (ALHs) 是OFP和SOAFP的主要贡献者.
- 可持续的RMA应用需要有针对性的排放抑制策略.
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