对化学共同沉合成的CoFe2O4纳米粒子进行研究,以在超偏磁阻断温度附近的磁热性能
Probal Roy1, S Manjura Hoque2, Sumi Akter1
1Department of Physics, Bangladesh University of Engineering and Technology, Dhaka- 1000, Bangladesh.
Heliyon
|July 31, 2024
概括
纳米尺寸的铁磁性纳米粒子显示了磁性制冷的潜力. 这些铁纳米粒子表现出有希望的磁热性质,包括显著的变化和相对冷却功率.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 磁力学 磁力学 是一种
背景情况:
- 铁 (CoFe2O4) 纳米颗粒通过共同沉方法进行合成.
- 在600°C的制过程中,可以提升晶体结构和磁性特性.
- 用特征技术来了解材料的行为.
研究的目的:
- 为了合成和表征纳米级磁性铁 (CoFe2O4) 纳米粒子.
- 研究磁性,包括铁磁性和超对磁性.
- 评估磁热效应,用于磁性制冷中的潜在应用.
主要方法:
- 共同沉合成,然后进行化.
- 用于晶体结构分析的X射线衍射 (XRD).
- 莫斯巴乌尔光谱仪用于磁性状态和地点占用率的确定.
- 振动样品磁力测量 (VSM) 用于磁性表征.
- 异热磁化测量用于磁热热效应评估.
主要成果:
- 通过XRD证实fcc型立方晶体结构的形成.
- 观测到铁磁性行为,与Mössbauer光谱学相一致.
- 在433 K.确定超偏磁阻塞温度.
- 在1.5 T时,最大变化 (ΔSmax) 为1.32 J/kg K,相对冷却功率 (RCP) 为52.22 J/kg.
- 分析了取决于频率的透性.
结论:
- 合成的CoFe2O4纳米粒子表现出有希望的磁性和磁热性质.
- 该材料展示了在降低温度下高效磁性制冷的潜力.
- 低应用磁场足以实现显著的冷却效应.
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