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Updated: Jun 18, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

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用于后离子电池的烯碳酸盐-金属盐电解液的扩散和结构:从实验到模拟

Argyrios V Karatrantos1,2, Maleen Middendorf3,4, Daniil R Nosov1,5

  • 1Luxembourg Institute of Science and Technology (LIST), 5 avenue des Hauts-Fourneaux, L-4362 Esch-sur-Alzette, Luxembourg.

The Journal of chemical physics
|August 1, 2024
PubMed
概括

有机电解质中的离子扩散会影响金属离子电池的性能. 这项研究揭示了阴离子大小如何影响溶剂和离子的移动性,这对于电池设计至关重要.

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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Electrolyte and Nonelectrolyte Solutions

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Formation of Complex Ions

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The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael...
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