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Updated: Jun 18, 2025

Measurement of the Potential Rates of Dissimilatory Nitrate Reduction to Ammonium Based on 14NH4+/15NH4+ Analyses via Sequential Conversion to N2O
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Measurement of the Potential Rates of Dissimilatory Nitrate Reduction to Ammonium Based on 14NH4+/15NH4+ Analyses via Sequential Conversion to N2O

Published on: October 7, 2020

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亚酸盐到氨的转化在中性介质中在白金表面上的电动力学

Md Fahamidul Islam1,2, Md Hassan Shahriar1, Mostafizur Rahaman3

  • 1Electrochemistry & Catalysis Research Laboratory (ECRL), Department of Chemistry, School of Physical Sciences, Shahjalal University of Science and Technology, Sylhet, 3114, Bangladesh.

Chemistry, an Asian journal
|August 1, 2024
PubMed
概括

这项研究证明了酸盐离子的电化学转化为氧化和氨,使用中性介质中的电极. 分析了反应动力学,揭示了一个不可逆转的,扩散控制的过程.

关键词:
激活能量是什么 激活能量是什么氨气 氨气 氨气 是一种运动学 运动学氧化氧化是什么?亚酸盐是一种酸盐.金电极是一种金电极.

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Secondary amines react with nitrous acid to form N-nitrosamines, as depicted in Figure 1. Nitrous acid, a weak and unstable acid, is formed in situ from an aqueous solution of sodium nitrite and strong acids, such as hydrochloric acid or sulfuric acid, in cold conditions. In the presence of an acid, the nitrous acid gets protonated. The subsequent loss of water results in the formation of the electrophile known as nitrosonium ion.
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