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Updated: Jun 18, 2025

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyltroponeiron
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Published on: August 12, 2019

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缺乏电子的化合物的氨基甲基化使铁光氧催化作用发挥作用

Aleksandra Ilic1, Benjamin R Strücker1, Catherine E Johnson2

  • 1Centre for Analysis and Synthesis (CAS), Department of Chemistry, Lund University SE-22100 Lund Sweden kenneth.warnmark@chem.lu.se.

Chemical science
|August 2, 2024
PubMed
概括

基于铁的光氧催化剂有效地使含有N的化合物的α功能化成为可能. 这项研究表明,地球上丰富的铁复合物利用可见光驱动有价值的合成转化,为贵金属催化剂提供了可持续的替代品.

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Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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