协同分子对齐和双极极化在拉伸纳/聚乙烯化物中) 混合膜用于PEMFC中的高质子导电
Iksu Lee1, Jaekeun Lee2, Dongjun Lee1
1Department of Advanced Materials, Hannam University, 1646 Yuseong-daero, Yuseong-gu, Daejeon 34054, Korea.
ACS applied materials & interfaces
|August 3, 2024
概括
机械拉伸对齐Nafion/PVDF混合膜,增强燃料电池的质子导电性. 这种结构对齐提高了质子交换膜燃料电池 (PEMFC) 的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 聚合物科学 聚合物科学
背景情况:
- 质子交换膜燃料电池 (PEMFC) 需要高效的质子导电膜.
- 纳和聚乙烯化物 (PVDF) 是膜开发中的关键材料.
- 控制膜纳米结构对于优化性能至关重要.
研究的目的:
- 通过使用机械单轴拉伸来调整Nafion/PVDF混合膜的纳米结构.
- 研究对齐的纳米结构和PVDF相变换对质子导电性的协同效应.
- 为了提高质子交换膜燃料电池 (PEMFC) 的性能.
主要方法:
- 纳/PVDF混合膜的机械单轴拉伸.
- 原子力显微镜 (AFM) 用于形态研究.
- 用于结构分析的小角度X射线散射 (SAXS).
主要成果:
- 成功调整了Nafion和PVDF纳米结构.
- 在Nafion中形成高度连接的水友性质子通道.
- PVDF从α相转变为β相,使F和H原子对齐.
- 由于对齐的纳米结构和PVDFβ相双极极化,增强了质子导电性.
- 在膜-催化剂层接口上提高了平面内质子导电性.
结论:
- 单轴拉伸有效地控制了Nafion/PVDF混合膜纳米结构.
- 组合的结构修改显著提高了质子导电性.
- 开发的膜在质子交换膜燃料电池 (PEMFCs) 中表现得更好.
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