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Updated: Jun 18, 2025

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

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替代剂对旋转交叉Fe(II) N4O2烯基化复合物的替代作用

Xuan Wang1, Nan Zhang1, Hui-Zhong Kou1

  • 1Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. kouhz@mail.tsinghua.edu.cn.

Dalton transactions (Cambridge, England : 2003)
|August 5, 2024
PubMed
概括

研究人员用pyrenylhydrazone配体合成了四种铁 (II) 复合物. 这些材料显示出分子开关和数据存储的潜力,具有不同的自旋状态和光特性.

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Valence Bond Theory

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An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0,...
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