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Updated: Jun 17, 2025

Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer
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Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer

Published on: November 30, 2020

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光化学 [2 + 2] 循环添加使得高热稳定性和抗酸/抗性聚合物的合成从一个非可聚合的α,β-合型烯酸

Chun Yang1, Xiao-Tong Wu1, Lefei Yu1

  • 1Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Department of Polymer Science and Engineering, College of Chemistry and Molecular Engineering, Centre for Soft Matter Science and Engineering, Peking University, Beijing 100871, China.

ACS macro letters
|August 5, 2024
PubMed
概括

研究人员通过光化学循环添加将一种非可聚合乳转化为可聚合的双循环乳. 这种方法产生了具有很好的水解耐受性的高热稳定性亚利法性聚合物,为先进材料提供了一条新的途径.

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Cycloadditions are one of the most valuable and effective synthesis routes to form cyclic compounds. These are concerted pericyclic reactions between two unsaturated compounds resulting in a cyclic product with two new σ bonds formed at the expense of π bonds. The [4 + 2] cycloaddition, known as the Diels–Alder reaction, is the most common. The other example is a [2 + 2] cycloaddition.
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