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Updated: Jun 17, 2025

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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Published on: April 4, 2014

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光催化汉茨奇乙介导的阿尔德和类的皮纳科尔型合

Hongjiang Li1, Chunxiang Pan1, Xinhan Li1

  • 1Yunnan Key Laboratory of Chiral Functional Substance Research and Application, Yunnan Minzu University, Kunming, Yunnan 650504, China.

The Journal of organic chemistry
|August 6, 2024
PubMed
概括

这项研究引入了一种新的无光催化剂反应,使用汉茨赫来将碳化合物合成1,2-二醇. 这种高效的方法适用于各种和在自我合和交叉合反应中.

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Wilhelm Rudolph Fittig discovered the pinacol coupling reaction in 1859. It is a radical dimerization reaction and involves the reductive coupling of aldehydes or ketones in the presence of hydrocarbon solvent to yield vicinal diols.
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The carbonyl center is...
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