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相关概念视频

Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

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Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
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Induced Electric Dipoles01:28

Induced Electric Dipoles

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A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
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Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

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The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
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由局部介电和诱导的集群形成在受限原始模型电解质中.

David Ribar1, Clifford E Woodward2, Sture Nordholm3

  • 1Computational Chemistry, Lund University, P.O. Box 124, S-221 00 Lund, Sweden.

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概括

经过修改的电解质模型显示,离子聚类导致缩盐溶液中的长距离电荷相互作用,解释了传统模型错过的实验发现.

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科学领域:

  • 物理化学 物理化学
  • 计算化学计算化学
  • 材料科学 材料科学 材料科学

背景情况:

  • 实验表明,在缩的盐溶液中,异常的电荷下面屏蔽.
  • 离子聚类是一个被提议的原因,但传统模型无法复制这种行为.

研究的目的:

  • 开发一个修改过的电解质模型,包括局部介电和.
  • 调查这个修改后的模型能否解释观测到的长距离电荷相互作用和离子聚类.

主要方法:

  • 修改限制原始模型以包括离子附近的介电和.
  • 在散装和裂几何学中进行模拟,以观察离子行为和密度相关性.
  • 基于实验盐溶解度的参数推断.

主要成果:

  • 修改后的模型显示了显著的离子集群形成.
  • 这些星团导致充电表面之间的长距离密度相关性,与实验观测结果相匹配.
  • 统一的介电模型,即使在低值,也没有显示类似的集群或相关性.

结论:

  • 局部介电和对于重现离子集群和长距离相互作用至关重要.
  • 观察到的现象是由集群-集群相关性驱动的,而不仅仅是增强的静电相互作用.
  • 修改后的模型更好地解释了在缩的电解质中实验下面的选.