持续发光波长的连续调整通过无机晶体中的中间相工程来进行
Xin Zhang1, Hao Suo1,2, Yang Guo1
1Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, China.
Nature communications
|August 9, 2024
概括
研究人员开发了一种新方法,可以精确调整Ca(Sr) ZnOS晶体中持续发光的颜色. 这一突破允许广泛的光谱控制和光学加密中的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态化学 固态化学
- 光电学是指光电子产品.
背景情况:
- 调整持久发光色对应用至关重要,但在现有材料中具有挑战性.
- 现有的方法往往涉及复杂的兴奋剂或材料组合.
- 在单相材料中精确的光谱控制仍然是一个未满足的需求.
研究的目的:
- 开发一种用于微调持久发光波长的新策略.
- 在单相晶体中设计子带隙的捐赠者-接受器状态.
- 为了实现对排放光谱的广泛而精确的控制.
主要方法:
- 合成具有不同Sr/Ca比率的单相Ca(Sr) ZnOS晶体.
- 持久发光性质的表征,包括光谱调整.
- 理论计算以了解底层电子结构的修改.
主要成果:
- 通过调整Sr/Ca比率,从500-630nm进行持续发光的近线性调整.
- 获得了大约5nm的光谱调整精度.
- 证明了高的初始发光度 (5.36 cd/m2在5秒) 和长时间的衰变时间 (长达6小时).
结论:
- 通过Sr合金的工程子频段间隙捐助者-接受者状态提供了有效的波长控制.
- 开发的Ca(Sr) ZnOS晶体提供了优越的,可调色的持续发光.
- 这种材料允许快速,可编程的模式,用于高通量光学加密.
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