在石英裂中的吸附行为,通过分子模拟
Bing You1, Jianfa Chen2, Xiaoqiang Liu3,4
1National Key Laboratory of Petroleum Resources and Engineering, College of Geosciences, China University of Petroleum, Beijing, 102249, China.
Scientific reports
|August 9, 2024
概括
在岩石中的吸附是复杂的. 在天然气迁移过程中,甲会取代,将集中在陷中,形成丰富的储,有助于资源评估.
科学领域:
- 地质化学 地质化学
- 地质物理学 地质物理学
- 材料科学 材料科学 材料科学
背景情况:
- 在地质条件下的矿物和岩石中吸附的理解很少.
- 物理化学性质,岩石学,温度和压力影响的行为.
- 了解吸附对于资源勘探至关重要.
研究的目的:
- 用分子模拟来研究石英中的吸附.
- 分析和甲之间的竞争性吸附.
- 阐明源岩中的保存和积累机制.
主要方法:
- 使用了大法典蒙特卡洛 (GCMC) 模拟.
- 模拟是在石英裂纹模型上进行的.
- 在地质条件下模拟纯和二元混合物 (-甲).
主要成果:
- 观察到在矿物表面的物理吸附,表明存在保存机制.
- 在石英中,甲的吸附性比的吸附性更强.
- 甲的竞争性吸附量随着埋藏深度的减少而增加,取代了.
结论:
- 是通过在源岩石中的物理吸附来保存的.
- 上升迁移的天然气会取代吸附的,导致其度.
- 这种移位机制解释了天然气储库中的积,为资源潜力的评估提供了信息.
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