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Updated: Jun 17, 2025

Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
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- 双环 - 基呈现出意想不到的反应性

Marie Sophie Würdemann1, Steffen Kühn1, Tobias Bötel1

  • 1Institute of Chemistry, Carl von Ossietzky Universität Oldenburg Carl von Ossietzky-Str. 9-11 D-26129 Oldenburg Federal Republic of Germany thomas.mueller@uni-oldenburg.de.

Chemical science
|August 12, 2024
PubMed
概括

新型的酸二环烯 (BCH) -基烯 (BCHGeGe) 是一种

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Pericyclic reactions are organic reactions that occur via a concerted mechanism without generating any intermediates. The reactions proceed through the movement of electrons in a closed loop to form a cyclic transition state, where rearrangement of the σ and π bonds yields specific products.
Pericyclic reactions can be classified into three categories: electrocyclic reactions, cycloaddition reactions, and sigmatropic rearrangements. Electrocyclic reactions and sigmatropic...
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