构造性变形的基于煤炭的活性碳及其表面修饰对甲吸附的影响
Xuan Huan1, Xiaojie Guo2, Xuexi Chen2
1Institute of Disaster Prevention Science and Safety Technology, No. 465, Xueyuan Street, Yanjiao High-tech Zone, Sanhe, Hebei 065201, P. R. China.
ACS omega
|August 12, 2024
概括
煤炭中的构造变形通过创建更小的孔隙来增强甲吸附. 表面的氧基,特别是氧基,显著降低了活性炭中的甲储存能力.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 地质地质地质地质地质地
背景情况:
- 基于煤的活性炭 (CAC) 对甲储存具有前景.
- 构造性变形煤 (TDC) 和初级结构性煤 (PSC) 在孔隙结构上有所不同.
- 了解这些差异是优化甲吸附材料的关键.
研究的目的:
- 从TDC和PSC中合成和描述CAC.
- 为了研究氧化修饰对孔隙结构和表面化学的影响.
- 为了确定这些修改对甲吸附能力的影响.
主要方法:
- 从密洛尼化脂肪煤 (TDC) 和PSC中合成活性炭.
- 使用低温吸附,FTIR,博姆定位和XPS进行表征.
- 甲吸附实验. 甲吸附的实验.
主要成果:
- 由TDC衍生的碳具有较小的孔径,特别是超微孔径,对于甲吸附至关重要.
- 对TDC碳的酸性修饰增加了孔隙参数和氧功能组.
- 酸治疗增加了孔积和SSA与碳素基;硫酸治疗增加了乳基并导致纳米孔堵塞.
- 增加的氧功能群显著降低了甲吸附能力,而孔隙腐蚀起到较小的作用.
结论:
- 构造变形显著影响煤炭的孔隙结构,影响甲吸附.
- 表面的氧功能组在降低甲吸附能力方面发挥着主导作用.
- 构造性煤炭资源为开发高性能甲储存材料提供了潜力.
更多相关视频
10:44Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
9.9K
10:27A Uniaxial Compression Experiment with CO2-Bearing Coal Using a Visualized and Constant-Volume Gas-Solid Coupling Test System
Published on: June 12, 2019
8.7K
相关概念视频
Carbon Skeletons
Life on Earth is carbon-based, as all macromolecules that make up living organisms contain carbon atoms. All organic compounds have a carbon backbone. Each carbon atom is tetravalent and can bond with four other atoms, making it an extraordinarily flexible component of biological molecules. Because carbon’s valence electrons are stable, it rarely becomes an ion. As the carbon chain increases in length, structural modifications such as ring structures, double bonds, and branching side chains...
The Carbon Cycle
Carbon is the basis of all organic matter on Earth, and is recycled through the ecosystem in two primary processes: one in which carbon is exchanged among living organisms, and one in which carbon is cycled over long periods of time through fossilized organic remains, weathering of rocks, and volcanic activity. Human activities, including increased agricultural practices and the burning of fossil fuels, has greatly affected the balance of the natural carbon cycle.
Catalysis
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
Heterogeneous Catalysis
Heterogeneous catalysis involves a catalyst in a different phase from the reactants. It is a process where the catalyst and the reactants are in distinct phases, typically solid and gas or liquid.Most heterogeneous catalysts are metals, metal oxides, or acids. The list includes transition metals like iron (Fe), cobalt (Co), nickel (Ni), palladium (Pd), platinum (Pt), chromium (Cr), manganese (Mn), tungsten (W), silver (Ag), and copper (Cu). These metals possess partially vacant d orbitals that...
Carbonation Shrinkage
Atmospheric CO2 penetrates the concrete's pores and, in the presence of moisture, forms carbonic acid, which then reacts with calcium hydroxide in the hydrated cement, forming calcium carbonate. This process reduces the concrete's volume and is termed carbonation shrinkage.
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction facilitates the...
The concrete's permeability is slightly reduced as calcium carbonate produced during the reaction fills its pores. Furthermore, its strength is slightly enhanced as the water released during the reaction facilitates the...
Carbon-dioxide Fixation
Carbon dioxide fixation in prokaryotes enables the assimilation of inorganic carbon into organic molecules, supporting biosynthetic pathways, sustaining ecosystems, and contributing to the global carbon cycle. It also has industrial applications in carbon capture and bioproduct synthesis. Autotrophic organisms rely on this process to utilize CO₂ as a carbon source in diverse environments.The Calvin CycleThe Calvin cycle is the most widespread carbon fixation mechanism, primarily used by...
