一个多功能pH依赖的度,色度和电化学传感器用于水中的H2S监测
Rashmi M Kulkarni1, M Ranjana1, Namratha Ullal1
1Department of Chemistry, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, Karnataka, 576104, India.
Journal of fluorescence
|August 13, 2024
概括
一个新型的探测器,NNAP,使用光,色度和电化学方法检测硫化 (H2S). 这种传感器在各种环境中有效进行实时监控.
科学领域:
- 分析化学 分析化学
- 环境科学 环境科学
- 生物化学 生物化学
背景情况:
- 硫化 (H2S) 是一种在水体和废水中发现的有毒气体.
- 高度的H2S在职业环境中构成健康风险.
- 准确和实时监测H2S对于安全至关重要.
研究的目的:
- 合成和描述一种用于H2S检测的新型探针 (NNAP).
- 评估NNAP的pH取决的传感能力.
- 展示NNAP在实时H2S监控中的实际应用.
主要方法:
- 合成的NNAP探测器. 的综合.
- 电化学,测色和光测量H2S的测量.
- 在不同的pH值 (2,7.4,12) 上测试NNAP性能.
- 开发NNAP涂层纸条用于现场监测.
主要成果:
- NNAP显示了pH值依赖的传感:pH值为7.4的度测量 (LOD为0.70毫米),pH值为12的色度测量 (LOD为4.28毫米),pH值为2的电化学测量 (LOD为2.5毫米).
- 在pH12下观察到可见的颜色变化,使得裸眼检测成为可能.
- 涂有NNAP涂层的纸条促进了成功的实时H2S监控.
结论:
- 该NNAP探头提供了H2S.的多功能和敏感的检测.
- 它的pH取决于响应允许适应性监测策略.
- NNAP是环境和职业监测的一个有前途的工具.
相关概念视频
Gas Chromatography: Types of Detectors-II
349
In gas chromatography, different detectors are employed to meet specific analytical needs. These detectors are often categorized based on their detection mechanisms and the types of compounds they are best suited to analyze. Thermal Conductivity Detectors (TCD), Flame Ionization Detectors (FID), and Electron Capture Detectors (ECD) represent common categories, each with unique operating principles and applications. However, beyond these, several other detectors are designed for more specialized...
349
Fluorescence and Phosphorescence: Instrumentation
560
Fluorometers and spectrofluorometers are two types of instruments used for measuring molecular fluorescence. These instruments differ in how they select excitation and emission wavelengths and the type of light sources they utilize. Fluorometers use absorption interference filters to choose excitation and emission wavelengths. The excitation source in a fluorometer is typically a low-pressure mercury vapor lamp that emits intense lines distributed throughout the ultraviolet and visible regions.
560
Indicators
48.5K
Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein is a colorless substance in any aqueous solution with a hydronium ion concentration greater than 5.0 × 10−9 M (pH < 8.3). In more basic solutions where the hydronium ion concentration is less than 5.0 × 10−9 M (pH > 8.3), it is red or pink. Substances such as phenolphthalein, which can be used to determine the pH of a solution, are...
48.5K
High-Performance Liquid Chromatography: Types of Detectors
512
The role of the detectors in High-Performance Liquid Chromatography (HPLC) is to analyze the solutes as they exit from the chromatographic column. The detector recognizes the solute's property and generates corresponding electrical signals, which are converted into a readable graph of the detector's response versus elution time called a chromatogram at the computer. There are several types of HPLC detectors, each with its own advantages and limitations, depending on the analyte...
512
Potentiometry: Types of Electrodes
562
Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the composition of a solution.
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
562
Photoluminescence: Applications
385
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
385


