纳米SiO2@PTPEG-VPA共聚物的合成及其对早期水泥水化的影响
Lei Dong1, Xin Shu2, Qianping Ran1,2
1Jiangsu Key Laboratory of Construction Materials, School of Material Science and Engineering, Southeast University Nanjing 211189 China leidong@seu.edu.cn.
RSC advances
|August 14, 2024
概括
用含的共聚合物 (PTPEG-VPA) 修改纳米 (纳米-SiO2) 的表面,有效地防止了水泥糊中的纳米粒子聚合. 这种化学接种增强了分散性,并影响了水泥的水化和早期力量的发展.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 土木工程 土木工程是指土木工程.
背景情况:
- 纳米二氧化 (nano-SiO2) 的结合提高了硬化水泥糊的性能.
- 在水泥孔溶液中的纳米颗粒聚合限制了成本效益的应用.
- 含酸盐的超级可塑剂显示出改善纳米粒子分散的潜力.
研究的目的:
- 开发一种表面化学修饰技术,以提高纳米SiO2的分散性.
- 调查改性纳米SiO2对水泥水化和早期强度的影响.
- 阐明修改纳米-SiO2.2观察到的影响背后的机制.
主要方法:
- 在纳米-SiO2.2上共聚化和化学接种聚异氧聚乙烯基醇 (PTPEG-VPA) 以太-随机-乙烯基酸 (PTPEG-VPA).
- 使用FT-IR,TGA,DLS,TEM,BET和zeta潜力进行SiO2@PTPEG-VPA纳米粒子的表征.
- 使用微热量计和TGA对水泥水化和早期强度的研究.
主要成果:
- 将PTPEG-VPA植入纳米SiO2上显著改善了纳米粒子分散,并减少了聚合.
- 修改后的纳米-SiO2 (SiO2@PTPEG-VPA) 影响了水泥水化动力学和早期的强度发展.
- 提出了一种解释移植PTPEG-VPA对原始SiO2减速作用的机制.
结论:
- 使用PTPEG-VPA进行表面化学修饰是提高纳米SiO2分散性的有效策略.
- 修改后的纳米-SiO2显示了改善水泥质性能的希望.
- 这项研究为操纵水泥材料性能的纳米粒子化学设计提供了新的见解.
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