密度,粘度和自我扩散系数的Octan-1-ol和相关的乙醇-酒精
Markus M Hoffmann1, Anthony A Gonzalez1, Mandy T Huynh1
1Department of Chemistry and Biochemistry, State University of New York Brockport, Brockport, New York 14420, United States.
Journal of chemical and engineering data
|August 14, 2024
概括
这项研究研究了以太醇,揭示了以太群的位置如何影响密度和动态. 乙烯基组通过键增加密度,而动态通常是更快的由于较弱的乙烯-氧--键.
科学领域:
- 物理化学 物理化学
- 有机化学 有机化学
- 材料科学 材料科学 材料科学
背景情况:
- 了解酒精和乙醇的结构-性质关系对于化学工程和材料科学至关重要.
- 乙醇代表了一类化合物,其潜在应用是希望修改结合和动态特性.
研究的目的:
- 研究八-1-醇和几个乙醇的热物理性质 (密度,粘度,自我扩散).
- 阐明由以太部分在酒精分子中的存在和位置影响的结构-属性关系.
- 评估水杂质对这些特性的影响.
主要方法:
- 实验测量密度,粘度和自我扩散系数.
- 基于分子结构和键的结构-属性相关性的分析.
- 阿雷尼乌斯分析以确定不同分子运动的激活能量.
主要成果:
- 乙醇的密度高于-1-,原因是分子间结的增加,而那些能够进行分子内结的醇的密度增加不那么明显.
- 与八-1-醇相比,以太醇通常表现出更快的动态,表明涉及以太氧的键较弱.
- 转换运动的激活能量高于动量转移的激活能量,在不同的乙醇中存在特定的变化.
结论:
- 以太部分显著影响结网络和酒精的动态.
- 分子结构,特别是以太群的分子内键的位置和潜力,决定了宏观性质.
- 水中的杂质会导致密度略微增加,并且根据分子的结能力对粘度有不同的影响.
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