相关实验视频
Updated: Jun 17, 2025

07:03
Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
10.6K
从KSrVO4:Er3+纳米的向上转换和向下转移发光,具有Judd-Ofelt参数
Meniak Khajuria1, Sajad A Bhat1, Shivam Kumar Mittal2
1School of Physics, Shri Mata Vaishno Devi University, Katra J&K, 182320, India.
Journal of fluorescence
|August 14, 2024
概括
这项研究合成了KSrVO4:Er3+体,用于冷LED应用. 该材料显示了对生物成像和光伏的有希望的上转换和下移发光.
科学领域:
- 固态化学 固态化学
- 发光光度 材料科学 材料科学
背景情况:
- 稀土合光体对于照明和先进光学应用至关重要.
- 了解发光机制是开发高效发光材料的关键.
研究的目的:
- 为了合成和描述与Er3+离子合的KSrVO4.
- 评估它们在酷LED应用,生物成像和光伏领域的潜力.
主要方法:
- 使用尿素作为燃料的燃烧合成.
- 用X射线衍射 (XRD) 和传输电子显微镜 (TEM) 进行结构和形态分析.
- 光学光谱学用于研究向上转换和向下转移的发光特性.
主要成果:
- 带有纳米尺度晶体体大小的正方形相 (大约. 21nm) 通过XRD.证实.
- 通过TEM观察到的球形和棒形形态.
- 在526,542,643 nm检测到上转换排放和492,544,680 nm检测到下转换排放.
- 由于双极-四极相互作用,临界火度为2.5mol%.
- 光学带间隙为3.61 eV (直接) 和3.41 eV (间接).
- 高颜色相关温度 (>5000 K) 表示适用于冷LED.
结论:
- KSrVO4:Er3+体表现出高效的向上转换和向下移动的发光.
- 该材料是冷白LED应用的有希望的候选材料.
- 由于其发光特性,在生物成像和光伏领域的潜在应用.
相关概念视频
Photoluminescence: Fluorescence and Phosphorescence
1.7K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
1.7K
Photoluminescence: Applications
385
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
385
UV–Vis Spectroscopy: Molecular Electronic Transitions
1.4K
In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this...
1.4K

