具有最相当的极化轴的无金属矿铁电材料
Zhi-Xu Zhang1, Hao-Fei Ni1, Jing-Song Tang1
1Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, People's Republic of China.
Journal of the American Chemical Society
|August 14, 2024
概括
无金属矿 (MFP) 现在具有24个极化轴的多轴铁电,这是铁电的最高数量. 这一突破为先进的应用提供了增强的压电传感性能.
科学领域:
- 材料科学
- 固态物理
- 晶体学
背景情况:
- 无金属矿因其环保性质和可加工性而具有吸引力.
- 具有多个极化轴的多轴铁电对于提高性能和应用多样性至关重要.
- 现有的MFP缺乏足够的等价极化轴,限制了它们的潜力.
研究的目的:
- 设计和合成新的多轴无金属矿铁电.
- 在MFP中实现最大可能的等价极化轴数.
- 展示设计材料的压电传感能力.
主要方法:
- 阳离子几何体的协同调节 (例如,I−,[PF6]−,[ClO4]−,[BF4]−) 和阴离子不对称的修饰.
- 多轴MFP铁电合成CMDABCO-NH4-X3 (X=[ClO4]−或[BF4]−).
- 确定晶体对称和极化轴的系统性表征.
主要成果:
- 成功设计了具有最低P1对称性的多轴MFP铁电CMDABCO-NH4-X3.
- 达到了24个等价极化轴 (Aizu符号432F1和m3̅mF1),这是铁电的最大值.
- 在CMDABCO-NH4-[ClO4]3多晶样品和复合器件中表现出卓越的压电传感性能.
结论:
- 已经制定了一个可行的多轴MFP铁电设计策略.
- 开发的MFP具有创纪录的极化轴数量,提高了它们的功能.
- 这些材料对微电机械,传感器和与身体相容的设备具有显著的前景.
相关概念视频
Dielectric Polarization in a Capacitor
4.6K
The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
4.6K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Potential Due to a Polarized Object
373
A neutral atom consists of a positively charged nucleus surrounded by a negatively charged electron cloud. When placed in an external electric field, the external electric force pulls the electrons and nucleus apart, opposite to the intrinsic attraction between the nucleus and the electrons. The opposing forces balance each other with a slight shift between the center of masses of the nucleus and the electron cloud, resulting in a polarized atom. On the other hand, a few molecules, like water,...
373
Induced Electric Dipoles
4.2K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.2K
Crystal Field Theory - Tetrahedral and Square Planar Complexes
41.8K
Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
41.8K
Magnetostatic Boundary Conditions
888
An electric field suffers a discontinuity at a surface charge. Similarly, a magnetic field is discontinuous at a surface current. The perpendicular component of a magnetic field is continuous across the interface of two magnetic mediums. In contrast, its parallel component, perpendicular to the current, is discontinuous by the amount equal to the product of the vacuum permeability and the surface current. Like the scalar potential in electrostatics, the vector potential is also continuous...
888


