在合金中的加多丰富相的微结构特征
Hyung-Ha Jin1, Sangeun Kim2, I Seul Ryu1
1Material Safety Technology Research Division, Korea Atomic Energy Research Institute, 111, Daedeok-daero 989 Beon-gil, Daejeon, 34057, Republic of Korea.
Heliyon
|August 15, 2024
概括
这项研究详细介绍了 (Ti) 合金中的加多 (Gd) 阶段形成,揭示了Gd氧化物和FCC型γ-Gd. 在Gd相和Ti矩阵之间的机械性能差异会产生缺陷,使合金变弱.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 物理化学 物理化学
背景情况:
- (Ti) 合金在各种行业中至关重要.
- 了解像加多 (Gd) 这样的合金元素的行为对于优化Ti合金性能至关重要.
- 富含加多的相可以显著影响Ti合金的微观结构和性能.
研究的目的:
- 综合研究合金中加多丰富相的微观结构特征.
- 阐明这些Gd阶段的形成机制和结晶学性质.
- 分析Gd相形成对Ti-Gd合金机械性能和加工的影响.
主要方法:
- 用于合金生产的等离子弧化和热造.
- 电子显微镜 (SEM,TEM) 用于微观结构分析.
- 电子反射散射衍射 (EBSD) 和能量分散光谱 (EDS) 用于相位识别和元素映射.
- 用于晶体分析的X射线衍射 (XRD).
主要成果:
- 形成圆形/角形的加多氧化物和长长的富含Gd的颗粒.
- 鉴定FCC类型的γ-Gd阶段和Gd2O3,受氧含量影响.
- 在Gd粒中观察内部双胞胎,可能抑制转化.
- 由于热加工过程中的机械性质不匹配而导致相位接口的缺陷,削弱了Gd相位.
结论:
- 该研究提供了关于Ti合金中Gd相形成的详细见解.
- 造过程中的氧气摄入对形成的Gd相的类型起着作用.
- Gd相与Ti矩阵之间的机械性能差异导致加工缺陷和Gd相强度降低.
- 增强对Ti-Gd合金行为的理解,以帮助未来的材料开发.
相关概念视频
Bonding in Metals
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”.
Metallic Solids
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Network Covalent Solids
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Complexation Equilibria: Factors Influencing Stability of Complexes
In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
Imperfections in Crystal Structure: Non-Stoichiometric Defects
Non-stoichiometric defects refer to a type of defect in the crystal structure of a compound where the ratio of its constituent elements deviates from the ideal stoichiometric ratio. There are two main types of non-stoichiometric defects: metal excess defects and metal deficiency defects.Metal excess defects occur when there is a slight surplus of metal ions than what is required by the stoichiometric ratio of the compound. For example, heating a sodium chloride crystal in sodium vapor results...
Fiber Reinforced Concrete
Fiber-reinforced concrete significantly enhances the structural and nonstructural properties of traditional concrete by incorporating fibers like steel, glass, and polymers. These fibers, varying from natural ones such as sisal and cellulose to manufactured ones like polypropylene and Kevlar, are mixed into hydraulic cement with aggregates. Steel fibers, often preferred for their robustness, contribute to improved ductility, toughness, and post-cracking performance. The concrete is classified...


