聚合物溶液薄膜的对流干燥:通过热量测量揭示了前部传播
Apolline Faidherbe1, Emmanuel Garre1, Maxence Wilmet2
1CNRS, Surface du Verre et Interfaces, Saint-Gobain, Aubervilliers 93300, France.
Langmuir : the ACS journal of surfaces and colloids
|August 15, 2024
概括
在控制的空气流中干燥的聚合物薄膜揭示了恒定速度的干燥前线. 这项研究使用热校准量化了干燥速度,通过质量平衡将前方速度与干燥动态联系起来.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 流体动力学 流体动力学
背景情况:
- 了解聚合物薄膜干燥对于制造工艺至关重要.
- 控制的空气流影响蒸发和薄膜特性.
研究的目的:
- 为了研究聚合物溶液薄膜在层状空气流下干燥的动态.
- 量化确定局部干燥速率和前部传播速度.
主要方法:
- 实验设置与受控的层状空气流.
- 在现场温度测量用于热校准.
- 使用保存定律和质量平衡原理进行分析.
主要成果:
- 一个明显的干燥前线以恒定的速度通过聚合物薄膜传播.
- 热校准允许对局部干燥速度进行定量测量.
- 实验性干燥速度与理论上的保护论据一致.
结论:
- 该研究确定了干燥前端速度和局部干燥速度之间的定量关系.
- 质量平衡原理有效地模拟了观察到的干燥现象.
- 研究结果为优化聚合物薄膜干燥过程提供了洞察力.
相关概念视频
Phase Transitions: Vaporization and Condensation
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules...
Step-Growth Polymerization: Overview
Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
Many natural and synthetic polymers are produced by...
Drying Shrinkage
When hardened concrete is exposed to air with a relative humidity of less than 100 percent, it begins to lose the free water within its capillaries. As this water evaporates, the water initially adsorbed onto the calcium silicate hydrates migrates towards these now empty spaces and eventually evaporates as well. Over time, as more water leaves, the volume of the concrete decreases, a phenomenon known as drying shrinkage.
A portion of this drying shrinkage can be reversed; if the concrete is...
A portion of this drying shrinkage can be reversed; if the concrete is...


