在分子水平上探测密封剂和粘附促进剂之间埋藏的接口结构上的盐水浸泡效应
Shuqing Zhang1,2, Na Fu3, Weibin Cui3
1Department of Macromolecular Science and Engineering, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, United States.
Langmuir : the ACS journal of surfaces and colloids
|August 16, 2024
概括
暴露在盐水中破坏了航空密封剂和粘附促进剂之间的接口,可能会影响粘附. 仅仅是高温并没有显著改变这种接口.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 频谱学是一种光谱学.
背景情况:
- 航空航天密封剂需要强大的粘合力来保持结构完整.
- 西兰粘附促进剂对于提高密封剂性能至关重要.
- 了解环境压力下的界面行为对于材料的耐用性至关重要.
研究的目的:
- 为了研究盐水和高温对醇环氧密封剂和西兰粘附促进剂 (6111) 的埋藏接口的影响.
- 阐明西兰成分在粘附中的作用及其界面相互作用.
- 为了确定环境压力因素对界面结构和潜在的粘附损失的影响.
主要方法:
- 总频率生成 (SFG) 振动光谱法用于分析埋藏的接口.
- 研究了一种与西兰粘附促进剂6111接触的模型硫醇环氧密封剂.
- 样品被暴露在3%的盐水中,在高温下,并且仅暴露在高温下.
主要成果:
- 暴露在盐水中导致密封剂/粘附促进剂接口发生显著变化.
- 单单高温 (60°C) 不会显著影响接口结构.
- 粘附促进剂中的氨基烯似乎比乙烯烯更能与密封剂分离和相互作用.
结论:
- 浸入盐水导致界面结构随机化,可能会损害粘附性.
- 特定的西兰成分影响界面相互作用和稳定性.
- 这些发现凸显了密封剂粘附促进器接口对盐水降解的脆弱性.
相关概念视频
Effect of Sea Water on Concrete
204
Concrete exposed to seawater can undergo degradation like the dissolution of ettringite and gypsum, increasing the material's porosity and decreasing its strength. In contrast, the crystallization of salts within the concrete's pores can cause expansion, particularly above the waterline where evaporation occurs. Nonetheless, this expansion only happens when seawater, enabled by the concrete's permeability, manages to infiltrate the structure.
Concrete in areas between tide marks,...
Concrete in areas between tide marks,...
204
Waterproofing and Anti-Bacterial Admixtures in Concrete
75
Concrete's susceptibility to water absorption is due to the capillary action within the pores of its hydrated cement paste. This action draws water in, creating the need for waterproofing admixtures to prevent such penetration. The efficacy of these admixtures is contingent upon the water pressure, with variations arising from different conditions such as rain, capillary rise, or hydrostatic pressure in structures intended to hold water.
Waterproofing admixtures render concrete hydrophobic,...
Waterproofing admixtures render concrete hydrophobic,...
75
Surface Tension, Capillary Action, and Viscosity
27.6K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
27.6K
Testing Water Quality
103
When the quality of water for concrete preparation is uncertain, its impact on the setting time of cement and compressive strength of mortar is assessed by comparison with de-ionized or distilled water benchmarks. American Society for Testing and Materials (ASTM) C1602 requires the setting times to be within 90 minutes of the control, British Standard (BS) 3146:1980 allows a 30-minute variance in the initial setting, while British Standards European Norm (BS EN) 1008 specifies initial setting...
103
Adhesion
39.8K
Adhesion occurs when one type of molecule is attracted to a different molecule. Water exhibits adhesive properties in the presence of polar surfaces, such as glass or cellulose in plants. For instance, when water is poured into a glass, the positively charged hydrogen molecules of water are more attracted to the negatively charged oxygen molecules in the silica than to the oxygen in neighboring water molecules.
Capillary action is a result of water’s adhesive tendencies. When a narrow...
Capillary action is a result of water’s adhesive tendencies. When a narrow...
39.8K


