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Updated: Jun 16, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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铜催化四组分多米诺循环化用于合成2 - 甲基二

Yanfeng Ma1, Tianci Xu1, Yuezhou Yuan1

  • 1Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Hunan Province Key Laboratory of Green Organic Synthesis and Application, College of Chemistry, Xiangtan University, Xiangtan 411105, China.

The Journal of organic chemistry
|August 17, 2024
PubMed
概括

一种新的单合成方法使用四组分多米诺循环生成非对称的2 - 甲基胺. 这种高效的铜催化反应产生了多种多替代的氨酸衍生物,具有各种功能组.

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.
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