使用离心机粘附平衡测量固体表面的表面能量
Appu Vinod1, Yuval Barak1, Sakshi Yadav Schmid2,3
1Department of Mechanical Engineering, <a href="https://ror.org/05tkyf982">Ben Gurion University</a>, Beer-Sheva 84105, Israel.
Physical review. E
|August 20, 2024
概括
这项研究引入了一种测量固体表面能量的新方法,避免了接触角度的不准确性. 新技术提供了更可靠的表面能量值和明智的极分散组件分解.
科学领域:
- 材料科学 材料科学 材料科学
- 表面化学 表面化学
- 物理化学 物理化学
背景情况:
- 标准的表面能量评估使用接触角度测量,这与热力学值不同.
- 这种差异导致了明显高估的表面能量预测,可能比实际值高出数百%.
- 现有的方法很难准确地确定表面能量的极性和分散成分.
研究的目的:
- 开发一种用于测量固体表面能量的新技术,克服接触角度测量的局限性.
- 为了准确地确定总表面能量及其极性和分散成分.
- 根据既有发现验证新方法,并提供更可靠的表面能量数据.
主要方法:
- 利用欧文-温特方法分析表面能量成分.
- 开发了一种采用固体-液体工作的粘合测量方法.
- 采用离心粘附平衡进行精确的测量,绕过接触角度的确定.
主要成果:
- 测量到的固体表面能量明显低于通过接触角度方法获得的表面能量.
- 新方法提供了表面能量的合理分解为极性和分散成分.
- 较高的极性成分与较多的极性固体正确相关,与以前的方法不同.
结论:
- 离心粘附平衡方法可以更准确地评估固体表面的能量.
- 这种技术提供了可靠的极性和分散的表面能量组件,对于材料特性至关重要.
- 这些发现挑战了对接触角度测量的传统依赖,以评估表面能量.
相关概念视频
Surface Tension and Surface Energy
1.3K
When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
1.3K
Surface Tension, Capillary Action, and Viscosity
27.6K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
27.6K
Contact Angle
12.3K
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
12.3K
Surface Tension of Fluid
255
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
Surface tension varies...
255
Frictional Force
7.9K
When a body is in motion, it encounters resistance because the body interacts with its surroundings. This resistance is known as friction, a common yet complex force whose behavior is still not completely understood. Friction opposes relative motion between systems in contact, but also allows us to move. Friction arises in part due to the roughness of surfaces in contact. For one object to move along a surface, it must rise to where the peaks of the surface can skip along the bottom of the...
7.9K
Adhesion
39.8K
Adhesion occurs when one type of molecule is attracted to a different molecule. Water exhibits adhesive properties in the presence of polar surfaces, such as glass or cellulose in plants. For instance, when water is poured into a glass, the positively charged hydrogen molecules of water are more attracted to the negatively charged oxygen molecules in the silica than to the oxygen in neighboring water molecules.
Capillary action is a result of water’s adhesive tendencies. When a narrow...
Capillary action is a result of water’s adhesive tendencies. When a narrow...
39.8K


