三维碳纳米管缓冲/碳阳极的界面应力,用于长周期储存
Hao Li1,2,3, Binghua Yao1, Ming Li2,3
1Department of Applied Chemistry, Xi'an University of Technology, Xi'an 710048, China.
ACS applied materials & interfaces
|August 20, 2024
概括
将碳纳米管引入/碳复合材料中可以增强离子电池阳极. 这一策略提高了高含量阳极的循环稳定性和速率能力.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术 纳米技术
背景情况:
- /石墨复合材料具有高的特异性容量,但由于体积膨胀和离子扩散的差异而遭受压力和电隔离.
- 这些问题限制了离子电池中的基阳极的性能和寿命.
研究的目的:
- 为离子电池开发一种新/碳复合材料的阳极材料.
- 通过减轻界面应力和提高导电性来增强阳极的循环稳定性和速率能力.
主要方法:
- 合成的/碳复合材料,采用碳纳米管 (CNTs),使用球磨和喷雾干燥.
- 研究了所得到的Si/CNTs/G@C-1阳极材料的结构和电化学特性.
主要成果:
- 引入CNT有效地减轻了/石墨界面的压力,形成了一个3D导电网络.
- Si/CNTs/G@C-1阳极表现出极好的循环性能,在500个循环后在1Ag-1下保持465mAhg-1.
- 实现了优越的速率能力,其容量为523mAhg-1在2Ag-1下.
结论:
- 开发的Si/CNTs/G@C-1复合阳极显著提高了离子电池的循环性能和速率能力.
- 这一策略为大规模生产高含量基纳米复合材料阳极提供了可行的方法.
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