在分散介质固化过程中,体颗粒之间出现长距离的吸引相互作用
Yujiro Furuta1,2, Rei Kurita1
1Department of Physics, Tokyo Metropolitan University, 1-1 Minamioosawa, Hachiouji-shi, Tokyo, Japan. furuta-yu@star.dnt.co.jp.
Soft matter
|August 20, 2024
概括
固化过程通过功能性合物增强聚合物产品. 分子动力学模拟揭示了粒子之间的远程吸引力,这对于控制聚合和推进制造至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 计算化学的计算化学
背景情况:
- 固化工艺比传统的干燥更有利于环境,减少挥发性有机化合物排放和能源消耗.
- 结合功能性合物 (抗病毒,导电) 增强了聚合物产品的特性,如油墨,涂料,复合材料和粘合剂.
- 固化过程中状颗粒的动力学和相互作用对材料特性至关重要,但仍然不太了解.
研究的目的:
- 研究在聚合物固化过程中分散介质内的软体颗粒的动力学和有效相互作用.
- 了解驱动粒子聚合超出随机接触的机制.
- 为了确定影响先进材料制造的合体排列的可控制因素.
主要方法:
- 利用分子动力学模拟来模拟散射介质中软颗粒的行为.
- 计算有效潜能来描述粒子间相互作用.
- 分析了固化速率和粒子扩散对聚合结构的影响.
主要成果:
- 与随机接触相比,在固化过程中观察到粒子聚合的可能性显著更高.
- 揭示了大型粒子之间的长距离吸引力相互作用,源于分散介质的交联网络中的异质性.
- 这种吸引力从根本上不同于经典的枯竭力.
结论:
- 在分散介质中的交联网络的异质性在固化过程中驱动着有吸引力的粒子间力量.
- 颗粒聚合结构可以通过平衡固化速率和颗粒扩散来控制.
- 结果为优化先进功能聚合物产品的制造提供了洞察力.
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