使用混合Sol-Gel催化剂进行可复制绿色合成
Rosaria Ciriminna1, Rafael Luque2, Mario Pagliaro1
1Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via U. La Malfa 153, 90146, Palermo, Italy.
Chemistry (Weinheim an der Bergstrasse, Germany)
|August 20, 2024
概括
使用SiliaCat混合型sol-gel催化剂的绿色合成在工业应用中取得了成功. 自动化合成和机器学习的进一步进步加速了优化和在精细化学工业中采用异质催化剂的速度.
科学领域:
- 绿色化学 绿色化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 纳米化学"自下而上"sol-gel方法的发展,利用有机改性来捕捉催化物种,已经建立了有效和多功能异质催化剂.
- 自20世纪90年代末以来,SiliaCat系列的混合型sol-gel催化剂一直在开发和应用.
研究的目的:
- 为了说明SiliaCat催化剂在具有工业意义的可重复绿色合成方法中的应用.
- 突出索尔凝异质催化剂从开发到先进应用的进展.
主要方法:
- 从2015年至2024年初发表的博士论文和研究作品中选择的例子进行审查.
- 专注于可重复的绿色合成和SiliaCat催化剂的工业应用.
主要成果:
- SiliaCat催化剂已成功应用于各种具有重要工业意义的绿色合成方法.
- 将这些催化剂集成到自动合成中,再加上机器学习,可显著加快和降低反应条件优化的成本.
结论:
- 异质催化剂的sol-gel方法已经被证明是成功和多功能.
- 自动化和机器学习方面的进步有望加速工业采用流下异质催化剂,克服精细化学工业以前的障碍.
相关概念视频
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
3.3K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.3K
Ziegler–Natta Chain-Growth Polymerization: Overview
3.2K
Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
3.2K


