石墨和金属电池电极的界面反应率的差异通过操作式气体分析进行了调查
J Padmanabhan Vivek1,2, Nuria Garcia-Araez1,2
1Chemistry, University of Southampton, Southampton SO17 1BJ, United Kingdom.
概括
来自电池的气体会影响安全. 乙烯气体是固体电解质相间形成的副产品,由金属电极消耗,形成聚烯,并指示新的SEI路径.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 电池技术 电池技术
背景情况:
- 来自电池的气态副产品显著影响性能和安全.
- 细胞胀是一个关键的安全问题,通常与电池内的气体演变有关.
- 了解气体形成对于开发更安全,更高效的电池至关重要.
研究的目的:
- 为了确定电池中产生的气体的类型和数量,使用石墨和金属电极.
- 为了研究乙烯气体的命运,固体电解质介相 (SEI) 形成的主要副产品.
- 阐明以前被忽视的SEI形成途径.
主要方法:
- 运行压力测量被用来实时监测气体积累.
- 在线电化学质谱 (OEMS) 用于识别演化气体的化学成分.
- 进行了对石墨电池与金属电极中的气体演变进行比较分析.
主要成果:
- 乙烯气是电池中SEI形成反应的重要副产品.
- 金属电极快速消耗乙烯气体,与石墨电极不同,除非经过预处理.
- 聚乙烯等多聚烯被确定为乙烯消耗的潜在产品,表明无气体SEI形成途径.
结论:
- 金属电极的乙烯消耗是SEI形成的新,无气路径.
- 这一发现挑战了以前关于SEI形成机制及其相关气体产品的假设.
- 了解这些气体消耗和形成途径对于减轻电池膨胀和提高安全至关重要.
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